FT-MIR supported Electrical Impedance Spectroscopy based study of sugar adulterated honeys from different floral origin

Publication date: 15 August 2017
Source:Talanta, Volume 171
Author(s): Chirantan Das, Subhadip Chakraborty, Krishnendu Acharya, Nirmal Kumar Bera, Dipankar Chattopadhyay, Anupam Karmakar, Sanatan Chattopadhyay
This study sought to detect the presence of sucrose as an adulterant in selected honey varieties from different floral origins by employing Electrical Impedance Spectroscopy (EIS) technique which has been simultaneously supported by Fourier Transform-Mid Infrared Spectroscopy (FT-MIR) measurements to provide a rapid, robust yet simple platform for honey quality evaluation. Variation of electrical parameters such as impedance, capacitance and conductance for 10%, 20%, 30%, 40%, 50%, 60% and 70% (w/w) sucrose syrup (SS) adulterated honey samples are analyzed and their respective current-voltage (I-V) characteristics are studied. Capacitance, conductance and net current flowing through the system are observed to decrease linearly whereas system impedance has been found to increase similarly with the increase in adulterant content. Also, FT-MIR measurements in the spectral region between 1800cm⁻¹ and 650cm⁻¹ reveal the increment of absorbance values due to the addition of SS. Full-Width-at-Half-Maximum (FWHM) is estimated from the spectral peak 1056cm⁻¹ for all pure and adulterated honey samples and is observed to be linearly increasing with increase in adulterant content. Finally, the coefficient of sensitivity has been extracted for all varieties of honey considered in terms of the measured conductance values.

Graphical abstract

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