Assembly of highly efficient photocatalytic CO2 conversion systems with ultrathin two-dimensional metal–organic framework nanosheets

Publication date: 5 July 2018
Source:Applied Catalysis B: Environmental, Volume 227
Author(s): Lu Ye, Yan Gao, Shuyan Cao, Hu Chen, Yanan Yao, Jungang Hou, Licheng Sun
An ultrathin two-dimensional Zn porphyrin-based metal–organic framework (Zn-MOF nanosheets) is developed and used for the first time in photoreduction of CO2 to CO. Consequently, two novelty noble-metal-free hybrid photocatalytic systems are established and displayed outstanding photocatalytic activity and selectivity for CO evolution under mild photocatalytic reaction conditions. The insight revealed Zn-MOF nanosheets as photosensitizer displays a better charge transport ability and longer lifetime of the photogenerated electron-hole pairs than the Zn-MOF bulk, which are confirmed by photoelectrochemical impedance and photoluminescence (PL) measurements. These studies show that the development of noble-metal-free photocatalytic systems and various MOF-based materials for photocatalytic applications are promising.

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