1-Ethyl-3-methylimidazolium tetrafluoroborate-doped high ionic conductivity gel electrolytes with reduced anodic reaction potentials for electrochromic devices

Publication date: 15 March 2017
Source:Materials & Design, Volume 118
Author(s): Quanfeng Tang, Haizeng Li, Yanfang Yue, Qinghong Zhang, Hongzhi Wang, Yaogang Li, Pei Chen
The electrolyte plays an important role in an electrochromic device (ECD), and an ideal electrolyte can greatly improve the electrochromic performance of the device. Here, we report the preparation of a 1-Ethyl-3-methylimidazolium tetrafluoroborate ([Emim]BF4)-doped Poly(methyl methacrylate) (PMMA)-based gel electrolyte for electrochromic applications. By the doping of the [Emim]BF4, the ionic conductivity of the gel electrolyte is improved (2.9×10⁻³S/cm at room temperature and 10⁻²S/cm at 40°C). Most importantly, the addition of the [Emim]BF4 could reduce the anodic reaction potentials in an ECD, which could enable ECD bleaching at smaller applied voltages and avoid the degradation of optical modulation induced by ion-trapping in tungsten oxide (WO3) films. This novel electrolyte provides a promising platform for low anodic reaction potential electrochromic devices.

Graphical abstract

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